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Sunday, January 2, 2022

The Novel Which I like Most

The novel that I like most is "The Old Man and The Sea". It caught my attention and tempted me to read it repeatedly. The story line is interesting and eye-catching. It tells the story of an old man who remains unsuccessful in catching a fish for 84  days but he doesn't give up. He is quite sure that he can catch a fish one day and works constantly in pursuit of it. He claims that man can be destroyed but can't be defeated.

The idea of this novel is that one should never give up even if the struggle is hard. We have to show perseverance. We must select a dream and work hard for making it possible for us. At the outset of this story we know that Santiago is assisted by a boy who is sent with him by a family to learn fishing. When Santiago fails to catch a fish for eighty four days, the family takes their child back and want him to go with another fisherman who has the luck of catching a fish. However, the boy proves to be loyal for Santiago. He often comes to help him.

Despite of all setback that Santiago experiences, he never thinks he cannot catch a fish. When the 84th day comes. He makes his mind to go as far as he can to catch the fish. Finally his luck smiles for him. He catches a fish but has still to fight with it. Because the fish is so big. It takes him two days to bring that fish to the shore. Although he takes skeleton to the shore because sharks attack and eat the flesh of fish, yet he has won the battle. He has caught the fish of big stature which nobody has done before. Tourists come to take pics and are attracted by the gaint fish. Everyone is surprised and the boy feels proud of Santiago.

This inspirational story has won my heart. I too feel that I'm like this old man who has to pursue a dream of achieving my aim. I also should work hard and should never give up. After all how can I forget "the man can be destroyed but can't be defeated".


MOLAR CONDUCTIVITY

 

MOLAR CONDUCTIVITY 

  • The conductivity  is defined as the conductivity of an electrolyte solution divided by molar concentration
  • Molar conductivity = λm = κ/c
  •  if k is expressed in Sm–1 and the concentration, c in mol m–3 then the unit of λm will be Sm2mol–1.
  •  If we use Scm–1 as the units for k and mol cm–3, the units of
  •  concentration, then the units for  λm  are Scm2mol–1. It can be calculated by using the equation:
  •  λm (Scm2mol–1) = κ(S cm–1) × 1000 (cm3/L)/molarity (mol/L).

ž OR, 1 Sm2mol–1 = 104 Scm2mol–1

Variation of molar conductivity of an ionic solution with concentration

 

Variation of molar conductivity of an ionic solution with concentration

  •  conductivity increases with increase in concentration since it depends on number of ions per volume.
  • Molar conductivity increases with decrease in concentration since it depends on mobility of ions.
  •  When concentration approaches zero, the molar conductivity is known as limiting molar conductivity and is represented by  m

Kohlrausch law of independent migration of ions and its applications

It states that limiting molar conductivity of an electrolyte  is the sum of the individual contributions of the anion and cation of the electrolyte.

ü  Thus, if λ°Na+ and λ°Cl -  are limiting molar conductivity of the sodium and  chloride ions , then the limiting molar conductivity for sodium  chloride is given by the equation:   

                     Ë°m(NaCl) = λ°Na+ + λ°Cl - 

Applications of Kohlrausch law 

This law may be used to determine the limiting molar conductivity, ‘λ°m’ degree of dissociation ‘α’ and dissociation constant ‘Ka’ of a weak electrolyte

Faraday’s Laws of Electrolysis

 

 (i) First Law: The amount of chemical reaction which occurs at any electrode during electrolysis by a current is proportional to the quantity of electricity passed through the electrolyte (solution or melt).

 (ii)Second Law: The amounts of different substances liberated by the same quantity of electricity passing through the electrolytic solution are proportional to their chemical equivalent weights (Atomic Mass of Metal ÷ Number of electrons required to reduce the cation).



Electrolytic cell

This is a device  which brings about a chemical change by means of electric current supplied. 

In this cell two electrodes are  dipped in same container.

 electricity from outside source supplies electrons for the non-spontaneous reaction.R

Reduction takes place cathode where metal from electrolytic solution gets deposited.

ü  oxidation takes place anode  from where metal goes into the electrolytic solution.




Corrosion And Prevention of corrosion

  •   Corrosion is the oxidative deterioration of metal.
  •   25% of steel produced goes to replace steel structures and products destroyed by corrosion.
  •  Rusting of iron requires the presence of both oxygen and water.
  •   Rusting results from tiny galvanic cells formed by water droplets.

Prevention of corrosion

  •  Galvanizing: is the coating of iron with zinc. Zinc is more easily oxidized than iron, which protects and reverses oxidation of the iron.
  •   Cathodic Protection: is the protection of a metal from corrosion by connecting it to a metal (a sacrificial anode e.g. Mg or Zn) that is more easily oxidized.
  •   Electroplating.
  •   By applying paint, grease, rubber to prevent contact of metal surface from air.



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