Popular Chemistry Online: To identify the functional group in the given organic compound

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Sunday, October 23, 2022

To identify the functional group in the given organic compound

Aim : To identify the functional group in the given organic compound.

Material Required : Test tube, test tube stand, test tube holder, dropper, litmus (blue), NaHCO3, conc. H2SO4 , NH4OH, FeCl3

Physical Properties:

State: Solid 

Color: White 

Odor: phenolic

Water solubility: insoluble

Flammability: Burn with non-sooty flame (Aliphatic) 

Preliminary test :

S.N.

Experiment

Observation

Inference

1.

Litmus test: Organic compound + 2 drops of litmus solution.

Litmus solution

turns from blue to red.

-COOH or phenolic

(–OH) may be present

2.

Organic compound + NaHCO3 solution.

No effervescence.

-COOH group absent

Phenolic (–OH) may

be present.

Confirmatory test :

S.N.

Experiment

Observation

Inference

1.

FeCl3 Test: Organic compound + dil. FeCl3 solution

Green blue or violet

coloration

Phenolic group is

confirmed

2.

Phthalic test: Organic compound + phthalic acid + 2-3 drops H2SO4 + D

then cool and add dil. NaOH

blue or red coloration

Phenolic group is confirmed

 

Result: The given organic comp. contains phenolic group.

           

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