Aim : To identify the functional group in the given organic compound.
Material Required : Test tube, test tube stand, test tube holder, dropper, litmus solution, 2,4 DNP, dil HCl, NaOH, reagent, Fehling solution, Schiff reagent.
Physical Properties:
State: liquid
Color: colourless
Odor: Pungent
Water solubility: soluble in water
Flammability: Burn with non-sooty flame (Aliphatic)
Preliminary test :
S.N. |
Experiment |
Observation |
Inference |
1. |
Litmus test: Organic
compound + 2 drops of
litmus solution. |
No change |
-COOH or phenolic (–OH) is present |
2. |
Organic compound + dil. HCl + NaOH |
No ppt or oily layer |
-NH2 group is absent. |
3. |
Organic compound + 2 ml
of 2,4-DNP shake it and allow to stand |
Orange-red ppt |
Carbonyl group is present Aldehyde or ketonic group may be present |
Confirmatory test :
S.N. |
Experiment |
Observation |
Inference |
1. |
Schiff's
solution test: Organic compound + 2 ml of Schiff's reagent. |
Pink color Obtained |
-CHO group present |
2. |
Fehling’s solution test:
Organic compound + Fehling’s solution (A + B) + boil in a water bath |
Red ppt. |
-CHO group present |
Result: Given organic compound contains aldehydic grp. (- CHO)
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